Sign In
Register
eISSN:2278-5299

International Journal of Latest Research in Science and Technology

DOI:10.29111/ijlrst   ISRA Impact Factor:3.35,  Peer-reviewed, Open-access Journal

A News Letter Sign UP!
INHIBITION OF CORROSION OF MILD STEEL IN H2SO4 SOLUTION BY SULFACHLOROPYRIDAZINE: SYNERGISM BY CATIONS AND HALIDES.

Research Paper Open Access

International Journal of Latest Research in Science and Technology Vol.4 Issue 2, pp 138-143,Year 2015

INHIBITION OF CORROSION OF MILD STEEL IN H2SO4 SOLUTION BY SULFACHLOROPYRIDAZINE: SYNERGISM BY CATIONS AND HALIDES.

O. A. Hazazi

Correspondence should be addressed to :

Received : 17 April 2015; Accepted : 22 April 2015 ; Published : 30 April 2015

Share
Download 125
View 180
Article No. 10509
Abstract

The synergism between sulfachloropyridazine (SCP), halides and/or copper ions on the inhibition of the corrosion of mild steel in 0.5 M H2SO4 solution has been studied using potentiodynamic measurements and electrochemical impedance spectroscopy (EIS). It has been found that the corrosion inhibition of mild steel by SCP is enhanced in the presence of halides and/or copper ions. SCP alone preferentially inhibits the anodic branch while Cu2+ + SCP inhibits the anodic branch and promote the cathodic one. However, the overall effect is that the inhibition efficiency in the latter case is larger than the former. In the presence of SCP + Cu2+ + halides, the inhibition efficiency is the largest and the promotion of the cathodic current by Cu2+ is overweighed by adding halides. Thus adding both Cu2+ and halides to SCP significantly inhibit the anodic branch while keeping the effect on the cathodic branch negligible. Experimental results fits with Langmuir isotherm.

Key Words   
Environmentally corrosion inhibitor; Langmuir isotherm; Mild steel; Synergism; sulfachloropyridazine

Copyright
References
  1. Zhang, M. Nie, . Wang, Y. Zhu, F. Shi , J. Yua and Baorong Hou, " Effect of molecular structure of aniline–formaldehyde copolymers on corrosion inhibition of mild steel in hydrochloric acid solution" J.  Haz. Mat. 289 (2015) 130–139.
  2. Mourya, S. Banerjee and M.M. Singh, "Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor", Corr. Sci. 85 (2014) 352–363.
  3. Bentiss, M. Lagrenee and M. Traisnel and J. C. Hornez, "The corrosion inhibition of mild steel in acidic media by a new triazole derivative", Corr. Sci. 41 (1999) 789–803.
  4. A. AbdEl-Maksoud and A.S. Fouda, "Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium", Mater. Chem. Phys. 93 (2005) 84–90.
  5. Keles, M. Keles, I. Dehri and O. Serindag, " The inhibitive effect of 6-amino-m-cresol and its Schiff base on the corrosion of mild steel in 0.5 M HCI medium", Mater. Chem. Phys. 112 (2008) 173–179.
  6. Wang, H. Fan and J. Zheng, " Corrosion inhibition of mild steel in hydrochloric acid solution by a mercaptotriazole Compound" Mater. Chem. Phys. 77 (2003) 655–661.
  7. Abdallah, " Ethoxylated fatty alcohols as corrosion inhibitors for dissolution of zinc in hydrochloric acid", Corros. Sci. 45 (2003) 2705–2716.
  8. Lagrenee, B. Mernari, M. Bouanis, M. Traisnel and F. Bentiss, "Study of the mechanism and inhibiting efficiency of 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media", Corr. Sci. 44 (2002) 573–588.
  9. A. Hegazy, M. Abdallah, M. K. Awad and M. Rezk, Three novel di-quaternary ammonium salts as corrosion inhibitors for API X65 steel pipeline in acidic solution, Part I: Experimental results, Corros. Sci. 81 (2014) 54–64.
  10. I. Ostapenko, P.A. Gloukhov and A.S. Bunev, " Investigation of 2-cyclohexenylcyclohexanone as steel corrosion inhibitor and surfactant in hydrochloric acid", Corr. Sci. 82 (2014) 265–270.
  11. Özcan, D. Toffoli, H. Üstünel and T. Dehri, "Insights into surface-adsorbate interactions in corrosion inhibition processes at the molecular level", Corr. Sci. 80 (2014) 482–486.
  12. Bobina, A. Kellenberger, J. P. Millet, C. Muntean and N. Vaszilcsin, "Corrosion resistance of carbon steel in weak acid solutions in the presence of L-histidine as corrosion inhibitor", Corros. Sci. 69 (2013) 389–395.
  13. B. Obot, Z.M. Gasem and S.A. Umoren, "Molecular level understanding of the mechanism of aloes leaves extract inhibition of low carbon steel corrosion: a DFT approach", Int. J. Electrochem. Sci. 9 (2014) 510–522.
  14. B. Raja, A.K. Qureshi, A.A. Rahim, H. Osman and K. Awang, "Neolamarckia cadamba alkaloids as eco-friendly corrosion inhibitors for mild steel in 1 M HCl media", Corr. Sci. 69 (2013) 292–301.
  15. M. Fares, A.K. Maayta and M.M. Al-Qudah, "Pectin as promising green corrosion inhibitor of aluminum in hydrochloric acid solution", Corr. Sci. 60 (2012) 112–117.
  16. Bentrah, Y. Rahali and A. Chala, "Gum Arabic as an eco-friendly inhibitor for API 5L X42 pipeline steel in HCl medium", Corr. Sci. 82 (2014) 426–431.
  17. A. Abu-Dalo, A.A. Othman and N.A.F. Al-Rawashdeh, "Exudate gum from acacia trees as green corrosion inhibitor for mild steel in acidic media", Int. J. Electrochem. Sci. 7 (2012) 9303–9324.
  18. Banerjee, V. Srivastava and M.M. Singh, "Chemically modified natural polysaccharide as green corrosion inhibitor for mild steel in acidic medium", Corr. Sci. 59 (2012) 35–41.
  19. Roy, A. Pal and D. Sukul, "Origin of the synergistic effect between polysaccharide and thiourea towards adsorption and corrosion inhibition for mild steel in sulphuric acid", RSC Adv. 4 (2014) 10607–10613.
  20. A. Hazazi, A. Fawzy and M. I. Awad, "Synergistic effect of halides on the corrosion inhibition of mild steel in H2SO4 by a triazole derivative: kinetics and thermodynamic studies", Int. J. Electrochem. Sci, 9 (2014) 4086.
  21. Khamis, M. M. Saleh, M. I. Awad and B.E. El-Anadouli "Inhibitory action of quaternary ammonium bromide on mild steel and synergistic effect with other halide ions in 0.5 M H2SO4", J. Adv. Res., 5 (2014) 637.
  22. A. Hazazi, A. Fawzy, M. R. Shaaban and M. I. Awad, "Enhanced 4-amino-5-methyl-4H-1,2,4-triazole-3-thiol Inhibition of Corrosion of Mild Steel in 0.5 M H2SO4 by Cu(II)" Int. J. Electrochem. Sci., 9 (2014) 1378.
  23. Khamis, M. M. Saleh, M. I. Awad and B.E. El-Anadouli, "Enhancing the inhibition action of cationic surfactant with sodium halides for mild steel in 0.5 M H2SO4", Corr. Sci., 74 (2013) 83-91.
  24. Khamis, M. M. Saleh and M. I. Awad, "Synergistic Inhibitor Effect of Cetylpyridinium Chloride and Other Halides on the Corrosion of Mild Steel in 0.5 M H2SO4",   Corr. Sci., 66 (2013) 343.
  25. Khamis, M. Saleh and M. I. Awad, "The counter ion influence of cationic surfactant and role of chloride ion synergism on corrosion inhibition of mild steel in acidic media", Int. J. Electrochem. Sci., 7 (2012) 10487 - 10500.
  26. I. Awad, "Eco friendly corrosion inhibitors: Inhibitive action of quinine for corrosion of low carbon steel in 1 M HCl", J. Appl. Electrochem., 36 (2006) 1163-1168.
  27. J. Wood, W. J. Marbel, M. Prystupa, M. J. Hudson and D. L. Wilkens, in: Proc. of 5th Inter. Conf. on Water Chemistry of Nuclear Reactor Systems, vol. 1, BNES, 1989, pp. 111–120.
  28. M. Angeliu and P. L. Andresen, " Effect of Zinc Additions on Oxide Rupture Strain and Repassivation Kinetics of Iron-Based Alloys in 288°C Water", Corrosion 52 (1996) 28–35.
  29. Aramaki, "The effect of modification with hydrogen peroxide on a hydrated cerium (III) oxide layer for protection of zinc against corrosion in 0.5 M NaCl", Corr. Sci. 48 (2006) 766–782.
  30. Notoya, V. Oteino-Alego and D. P. Schweinsberg, "The corrosion and polarization behaviour of copper in domestic water in the presence of Ca, Mg and Na-salts of phytic acid, Corr. Sci. 37 (1995) 55–65.
  31. M. Drazic and L. Z. Vorkapic, "Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions", Corr. Sci. 18 (1978) 907.
  32. S. Abdel Aal and M. H. Wahdan, Br. Corr. J. (1998) 25.
  33. Leidheiser, I. Suzuki, " Cobalt and Nickel Cations as Corrosion Inhibitors for Galvanized Steel", J. Electrochem. Soc. 128 (1981) 242.
  34. Wahdan, "The synergistic inhibition effect and thermodynamic properties of 2-mercaptobenzimidazol and some selected cations as a mixed inhibitor for pickling of mild steel in acid solution", Mater. Chem. Phys. 49 (1997) 135.
  35. Duprat and F. Dabos, in: Proceedings of the Fifth SEIC, Ferrara, Italy, 1980, p. 675.
  36. M. West, in " Electrodeposition and Corrosion Process", second ed., Van Nostrand-Reinhold, London,1970. p.93.
  37. Qiang and C. Adams, " Potentiometric determination of acid dissociation constants (pKa) for human and veterinary antibiotics", Water Res 2004, 38, 2874-2890.
  38. S. Iqbal,A. H. Khan and  B. A. Loother, "Comparative study of pharmaceutical properties of some new derivatives of sulfamethoxazole", Pharm Dev Technol. 15 (2010) 613-618.
  39. K. Nørskov,T. Bligaard, A. Logadottir, J. R. Kitchin, J. G. Chen, S. Pandelov and U. Stimming, " Trends in the Exchange Current for Hydrogen Evolution", J. Electrochem. Soc., 152 (2005) J23-J26.
  40. Lebrini, F. Robert and C. Roos, " Inhibition Effect of Alkaloids Extract from Annona Squamosa Plant on the Corrosion of C38 Steel in Normal Hydrochloric Acid Medium", Int J Electrochem Sci 5 (2010) 1698–1712.
  41. B. Growcoc and R. I. Jasinski, "Time‐Resolved Impedance Spectroscopy of Mild Steel in Concentrated Hydrochloric Acid", J Electrochem Soc 136 (1989) 2310–2314.
  42. K. Yadav and M. A. Quraishi, " Electrochemical investigation of Substituted Pyranopyrazoles Adsorption on Mild Steel in Acid Solution", Ind Eng Chem Res 2012, 51, 8194-8210.
  43. E. Ebenso, I. B. Obot and L. C. Murulana, " Quinoline and its Derivatives as Effective Corrosion Inhibitors for Mild Steel in Acidic Medium ",Int J Electrochem Sci 2010, 5, 1574-1586.
  44. Tourabi, K. Nohair, M. Traisnel, C. Jama and F. Bentiss , " Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole", Corros Sci 2013, 75,123-133.
  45. Moretti, F. Guidi and G. Grion, "Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid", Corr. Sci. 46 (2004) 387-403.
To cite this article

O. A. Hazazi , " Inhibition Of Corrosion Of Mild Steel In H2so4 Solution By Sulfachloropyridazine: Synergism By Cations And Halides. ", International Journal of Latest Research in Science and Technology . Vol. 4, Issue 2, pp 138-143 , 2015

Responsive image

MNK Publication was founded in 2012 to upholder revolutionary ideas that would advance the research and practice of business and management. Today, we comply with to advance fresh thinking in latest scientific fields where we think we can make a real difference and growth now also including medical and social care, education,management and engineering.

Responsive image

We offers several opportunities for partnership and tie-up with individual, corporate and organizational level. We are working on the open access platform. Editors, authors, readers, librarians and conference organizer can work together. We are giving open opportunities to all. Our team is always willing to work and collaborate to promote open access publication.

Responsive image

Our Journals provide one of the strongest International open access platform for research communities. Our conference proceeding services provide conference organizers a privileged platform for publishing extended conference papers as journal publications. It is deliberated to disseminate scientific research and to establish long term International collaborations and partnerships with academic communities and conference organizers.