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International Journal of Latest Research in Science and Technology

DOI:10.29111/ijlrst   ISRA Impact Factor:3.35,  Peer-reviewed, Open-access Journal

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EFFECT OF SURFACTANTS ON THE THERMAL DECOMPOSITION OF Li7La3Zr2O12 CERAMICS POWDER

Research Paper Open Access

International Journal of Latest Research in Science and Technology Vol.2 Issue 6, pp 49-52,Year 2013

EFFECT OF SURFACTANTS ON THE THERMAL DECOMPOSITION OF LI7LA3ZR2O12 CERAMICS POWDER

Lukman Hakim Hussin, Mohd Hafiz Yaakob, Nafisah Osman, Nurul Asyikin Mazlan

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Received : 24 December 2013; Accepted : 27 December 2013 ; Published : 31 December 2013

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Abstract

Ceramics powder of Li7La3Zr2O12 (LLZ) was prepared by a sol-gel method from the stoichiometric mixtures of nitrate salt as precursor. The LLZ resin was heated at temperature of 325ï‚°C for 2 hours and at various calcination temperatures between 600-900 ï‚°C for 10 hours. The powders obtained were characterized by Thermal Gravimetry Analysis (TGA) and Fourier Transform Infrared (FTIR) to verify the thermal decomposition of the powders and the presence of carbonate group in the compound. TGA results indicate that all the samples were almost completely decomposed at ~800 ï‚°C except for sample with CTAB surfactant that showed the lowest thermal decomposition temperature at 733 ï‚°C. FTIR analysis showed that the intensity of carbonate group were decreased due to the increasing of temperature. It was found that the different surfactants used lead to the different characteristics of the LLZ powder.

Key Words   
LLZ ceramics powder, modified sol-gel method, surfactants, thermal decomposition

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References
  1. Kumazaki Shota, Iriyama Yasutoshi, Kim Ki-Hyun, Murugan Ramaswamy, Tanabe Kinuka, Yamamoto Kazuo, Ogumi Zempachi. (2011). High lithium ion conductive Li7La3Zr2O12 by inclusion of both Al and Si. Electrochemistry Communications, 13(5), 509-512.
  2. Saranya K., Deviannapoorani C., Dhivya L., Ramakumar S., Janani N., & Murugan R. (2012). Li7-xLa3Sn2-xNbxO12(x=0.25–1) cubic lithium garnet. Materials Letters, 77, 57-59.
  3. Janani, N., Ramakumar, S., Dhivya, L., Deviannapoorani, C., Saranya, K., & Murugan, R. (2011). Synthesis of cubic Li7La3Zr2O12 by modified sol–gel process. Ionics, 17(7), 575-580.
  4. Le, J., van Rij, L. N., van Landschoot, R. C., & Schoonman, J. (1999). A wet-chemical method for the synthesis of in-doped CaZrO3 ceramic powders. Journal of the European Ceramic Society, 19(15), 2589-2591.
  5. Barison, S., Fabrizio, M., Fasolin, S., Montagner, F., & Mortalò, C. (2010). A microwave-assisted sol–gel Pechini method for the synthesis of BaCe0.65Zr0.20Y0.15O3−δ powders. Materials Research Bulletin, 45(9),1171-1176.
  6. Abdullah, N. A., Osman, N., Hasan, S., & Nordin, R. M. (2012). The Effect of Various Chelating Agents on the Thermal Decomposition of Cerate-Zirconate Ceramics Powder. APCBEE Procedia, 3(0), 28-32.
  7. Khani, Zohreh, Taillades-Jacquin, Mélanie, Taillades, Gilles, Marrony, Mathieu, Jones, Deborah J., & Rozière, Jacques. (2009). New synthesis of nanopowders of proton conducting materials. A route to densified proton ceramics. Journal of Solid State Chemistry, 182(4), 790-798.
  8. Wang, Zaihua, Li, Xinjun, & Feng, Ziping. (2011). The Effect of CTAB on the Citrate Sol-gel Process for the Synthesis of Sodium Beta-Alumina Nano-Powders. Korean Chem. Soc, 32(4), 1311.
  9. Qiu, Shaojun, Gao, Chao, Zheng, Xiaodong, Chen, Jin, Yang, Chen, Gan, Xiaoxian, & Fan, Huiqing. (2008). Pb(Zr0.95Ti0.05)O3 powders prepared by aqueous Pechini method using one-step pyrolysis process: characterization and porous ceramics. Journal of Materials Science, 43(9), 3094-3100.
  10. Pechini, MP. (1967). Method of preparing lead and alkaline earth titanates and niobates and coating method using the same to form a capacitor: US, 3330697.
To cite this article

Lukman Hakim Hussin, Mohd Hafiz Yaakob, Nafisah Osman, Nurul Asyikin Mazlan , " Effect Of Surfactants On The Thermal Decomposition Of Li7la3zr2o12 Ceramics Powder ", International Journal of Latest Research in Science and Technology . Vol. 2, Issue 6, pp 49-52 , 2013

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